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Making Biofuel Modeling Stick

 

By Mikko Hupa, Christian Mueller, and Anders Brink, Åbo Akademi University, Finland

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Over the years, CFD has been widely used for optimizing the design and operation of coal combustion systems, and a number of useful submodels have been developed to describe the various combustion details of coal particles. In addition to coal, biofuels have become increasingly utilized in large-scale combustion facilities as well. They differ from coal in several ways, and submodels specifically designed for coal combustion cannot be applied to biofuels. At the Åbo Akademi University in Finland, researchers are working to develop improved CFD models and submodels for a variety of biofuel combustion systems, such as fluidized beds and black liquor recovery boilers. These models are in the form of user-defined functions (UDFs) for FLUENT 6.1.

Nitrogen oxide (NO) chemistry in biofuel systems differs from that in coal systems due to the fact that the principle volatile fuel nitrogen compound in biofuels is ammonia (NH3), rather than hydrogen cyanide (HCN), which is the dominant source in coal combustion. Åbo Akademi engineers have developed a novel, fast submodel to describe the conversion of the biofuel’s ammonia into NO. The model is derived from comprehensive kinetic reaction schemes, and has given realistic predictions (within 15%) of the NO formation in the free board of a fluidized bed combustor (FBC).

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Furnace free board NOx distribution calculated with FLUENT and the ÅA biomass NOx submodel in a 270 MWth bubbling fluidized bed boiler fired with wood waste and peat

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Impaction maps of fly ash particles hitting furnace walls; a photograph of one of the walls indicates that wall fouling takes place in the area of the hottest particle impactions

Ash particles from biofuel combustion are chemically very reactive and may cause severe fouling of heat exchanger surfaces. Åbo Akademi’s novel routine for biomass ash particle behavior can be used to study the consequences of ash particles impacting on different boiler surfaces, and to establish whether the particles are in the necessary chemical and physical states to cause them to either stick on the surface or bounce back into the gas flow.

The biomass combustion research is part of the four-year research program CODE, which was recently completed in Finland. This program consisted of some fifty research projects in various research laboratories and universities throughout the country. The program was aimed at developing improved CFD methodologies for large-scale combustion systems. The total expenditure for the program in 1999-2002 was 12.6 million Euros, of which roughly half came from the National Technology Agency of Finland, Tekes, and half from the participating companies. Fluent provided support to the program in the form of software and technical exchange.

Editor’s note: Professor Mikko Hupa was the scientific advisor of the CODE research program in Finland.

References:

  • A. Brink, P. Kilpinen, and M. Hupa, Energy & Fuels, 15(5), p. 1094-1099, 2001.
  • C. Mueller, D. Lundmark, B.-J. Skrifvars, R. Backman, M. Zevenhoven, and M. Hupa, CFD Based Ash Deposition Prediction in a BFB Firing Mixtures of Peat and Forest Residue, 17th Int. Conf. on Fluidized Bed Combustion, Jacksonville, 2003.

More Information

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